1 00:00:00,790 --> 00:00:07,210 [Music] 2 00:00:11,780 --> 00:00:09,620 for those of you who don't know me I'm 3 00:00:14,990 --> 00:00:11,790 Jay crawl I also go by Alec that's how 4 00:00:16,760 --> 00:00:15,000 you'll find me on social media I use 5 00:00:20,000 --> 00:00:16,770 masculine gender pronouns he has in him 6 00:00:21,650 --> 00:00:20,010 and I study I'm a graduate student at 7 00:00:24,320 --> 00:00:21,660 the University of Colorado where I study 8 00:00:26,859 --> 00:00:24,330 one how gender and sexuality affect the 9 00:00:29,990 --> 00:00:26,869 academic outcomes for Gen chem students 10 00:00:32,150 --> 00:00:30,000 more topically I also study sulfur 11 00:00:34,700 --> 00:00:32,160 reactions and atmospheres in planetary 12 00:00:36,020 --> 00:00:34,710 atmospheres I'm not going to talk to you 13 00:00:38,270 --> 00:00:36,030 about either of those things this 14 00:00:46,270 --> 00:00:38,280 morning I'm going to talk to you about 15 00:00:53,860 --> 00:00:52,069 rocks cool so more specifically I'm 16 00:00:55,850 --> 00:00:53,870 going to talk to you a little bit about 17 00:00:57,590 --> 00:00:55,860 some of the rocks that you're going to 18 00:00:59,380 --> 00:00:57,600 hear about in this morning's session and 19 00:01:01,819 --> 00:00:59,390 why we care about them as 20 00:01:05,000 --> 00:01:01,829 astrobiologists to the geologists in the 21 00:01:10,070 --> 00:01:05,010 room please forgive me and correct me 22 00:01:11,270 --> 00:01:10,080 during the session after so the first 23 00:01:14,090 --> 00:01:11,280 rock that we're going to talk about is 24 00:01:16,670 --> 00:01:14,100 Venus it's often referred to as Earth's 25 00:01:18,649 --> 00:01:16,680 twin more accurately it might be 26 00:01:22,550 --> 00:01:18,659 described as our evil twin on a bad hair 27 00:01:25,760 --> 00:01:22,560 day but it's very similar to earth in 28 00:01:27,530 --> 00:01:25,770 size and mass and Composition but a 29 00:01:29,780 --> 00:01:27,540 couple of things make it very notably 30 00:01:31,749 --> 00:01:29,790 different especially at sulfuric acid 31 00:01:35,899 --> 00:01:31,759 clouds so from about 50 to 70 kilometers 32 00:01:39,440 --> 00:01:35,909 there's a global sulfuric acid cloud 33 00:01:42,200 --> 00:01:39,450 layer it also has an incredibly slow day 34 00:01:45,230 --> 00:01:42,210 so it takes about 243 Earth days for 35 00:01:46,730 --> 00:01:45,240 Venus to turn once on its axis and it 36 00:01:49,520 --> 00:01:46,740 also rotates in the opposite direction 37 00:01:51,289 --> 00:01:49,530 of all the other planets this is likely 38 00:01:56,450 --> 00:01:51,299 because of some massive cataclysmic 39 00:01:58,880 --> 00:01:56,460 collision or earlier in its history it 40 00:02:03,800 --> 00:01:58,890 also is incredibly hot at its surface 41 00:02:06,200 --> 00:02:03,810 about 500 degrees Celsius and if we take 42 00:02:08,210 --> 00:02:06,210 a look at its atmosphere that's a little 43 00:02:10,760 --> 00:02:08,220 bit easier to explain the surface 44 00:02:12,470 --> 00:02:10,770 pressure is 93 bar it's almost 100 times 45 00:02:12,830 --> 00:02:12,480 more pressure at its surface than on 46 00:02:15,559 --> 00:02:12,840 earth 47 00:02:18,050 --> 00:02:15,569 and that atmosphere is almost entirely 48 00:02:19,550 --> 00:02:18,060 carbon dioxide and so it has this 49 00:02:22,880 --> 00:02:19,560 incredibly potent greenhouse gas 50 00:02:26,270 --> 00:02:22,890 atmosphere there's some nitrogen as well 51 00:02:30,229 --> 00:02:26,280 as some other trace gases most notably 52 00:02:32,150 --> 00:02:30,239 so2 but because of that global cloud 53 00:02:35,449 --> 00:02:32,160 cover it has this incredibly high albedo 54 00:02:37,759 --> 00:02:35,459 which means that almost 90% of the light 55 00:02:39,920 --> 00:02:37,769 that is in coming from the Sun actually 56 00:02:41,509 --> 00:02:39,930 gets reflected away from Venus but the 57 00:02:44,420 --> 00:02:41,519 atmosphere is so thick that even that 58 00:02:46,970 --> 00:02:44,430 10% that gets in and absorbed by the 59 00:02:50,420 --> 00:02:46,980 planet leads to incredible heating of 60 00:02:52,460 --> 00:02:50,430 the surface there's also very little 61 00:02:56,300 --> 00:02:52,470 hydrogen and Venus's atmosphere and 62 00:02:58,610 --> 00:02:56,310 there's an incredibly high d2h ratio and 63 00:03:00,259 --> 00:02:58,620 so what that tells us is that actually 64 00:03:03,229 --> 00:03:00,269 Venus has probably lost a lot of the 65 00:03:05,210 --> 00:03:03,239 water from it which is interesting 66 00:03:07,039 --> 00:03:05,220 because early on its history we think 67 00:03:10,210 --> 00:03:07,049 Venus may have been a lot more like 68 00:03:12,830 --> 00:03:10,220 Earth and had oceans on its surface 69 00:03:18,020 --> 00:03:12,840 today its surface looks incredibly 70 00:03:21,650 --> 00:03:18,030 different though there is because of its 71 00:03:23,330 --> 00:03:21,660 similar size and density we assume that 72 00:03:26,539 --> 00:03:23,340 it's pretty similar to earth and that it 73 00:03:28,280 --> 00:03:26,549 has a core a mantle and a crust however 74 00:03:30,259 --> 00:03:28,290 we don't have a lot of actual direct 75 00:03:33,500 --> 00:03:30,269 evidence about the internal structure of 76 00:03:34,910 --> 00:03:33,510 the planet we don't see any evidence of 77 00:03:36,920 --> 00:03:34,920 plate tectonics which is pretty 78 00:03:41,690 --> 00:03:36,930 interesting and there's no magnetic 79 00:03:44,420 --> 00:03:41,700 field however most of the impact craters 80 00:03:47,660 --> 00:03:44,430 are almost in pristine condition the 81 00:03:49,039 --> 00:03:47,670 surface is very young only about 300 to 82 00:03:51,080 --> 00:03:49,049 600 million years old 83 00:03:54,080 --> 00:03:51,090 and there's been a lot of evidence of 84 00:03:56,420 --> 00:03:54,090 past volcanic activity and so what we 85 00:03:59,660 --> 00:03:56,430 think happens on Venus is that the crust 86 00:04:02,390 --> 00:03:59,670 is doesn't we don't have any of these 87 00:04:04,099 --> 00:04:02,400 plate tectonics right now but the mantle 88 00:04:06,080 --> 00:04:04,109 slowly heats up and at some point 89 00:04:08,090 --> 00:04:06,090 there's enough to actually enough energy 90 00:04:10,280 --> 00:04:08,100 to actually disrupt the crust and then 91 00:04:14,740 --> 00:04:10,290 we see massive turnover of the surface 92 00:04:17,090 --> 00:04:14,750 and resurfacing of the entire planet 93 00:04:19,009 --> 00:04:17,100 with so if we go a little bit farther 94 00:04:21,670 --> 00:04:19,019 out in our solar system we've got Titan 95 00:04:24,469 --> 00:04:21,680 it's the largest moon orbiting Saturn 96 00:04:25,980 --> 00:04:24,479 but perhaps most interesting is that 97 00:04:30,120 --> 00:04:25,990 it's the only moon with a 98 00:04:34,189 --> 00:04:30,130 atmosphere and the surface is composed 99 00:04:37,320 --> 00:04:34,199 mostly of water ice and rocky material 100 00:04:39,300 --> 00:04:37,330 but this dense atmosphere is possibly an 101 00:04:40,350 --> 00:04:39,310 analogue to early Earth's atmosphere 102 00:04:44,040 --> 00:04:40,360 which is what makes it really 103 00:04:46,620 --> 00:04:44,050 interesting to us as astrobiologists and 104 00:04:48,990 --> 00:04:46,630 so its atmosphere actually has a very 105 00:04:50,460 --> 00:04:49,000 similar structure to Earth it has this 106 00:04:53,129 --> 00:04:50,470 troposphere where we see all of its 107 00:04:54,960 --> 00:04:53,139 weather and then an upper stratosphere 108 00:04:58,260 --> 00:04:54,970 where there's a stolen haze which is 109 00:05:00,629 --> 00:04:58,270 mostly carbon containing organics with 110 00:05:03,240 --> 00:05:00,639 some nitrogen in them and then a miso 111 00:05:05,939 --> 00:05:03,250 sphere and thermosphere its atmosphere 112 00:05:09,180 --> 00:05:05,949 is almost 90 almost entirely nitrogen 113 00:05:10,350 --> 00:05:09,190 it's about 98% nitrogen we do see some 114 00:05:13,080 --> 00:05:10,360 methane 115 00:05:15,060 --> 00:05:13,090 it's 1.2 percent overall but as you go 116 00:05:18,089 --> 00:05:15,070 closer to the surface actually increases 117 00:05:20,909 --> 00:05:18,099 to about 5% of the atmosphere and that's 118 00:05:22,620 --> 00:05:20,919 because it's incredibly cold and so that 119 00:05:24,540 --> 00:05:22,630 methane actually begins to freeze out 120 00:05:28,550 --> 00:05:24,550 and you get precipitation of it on the 121 00:05:31,680 --> 00:05:28,560 planet in this lower troposphere and 122 00:05:33,210 --> 00:05:31,690 there's a little bit of hydrogen and 123 00:05:35,010 --> 00:05:33,220 then there's a lot of trace organics 124 00:05:40,550 --> 00:05:35,020 formed because of the photo chemistry 125 00:05:42,930 --> 00:05:40,560 that goes on with methane before Cassini 126 00:05:46,350 --> 00:05:42,940 cassini-huygens we actually did not know 127 00:05:48,060 --> 00:05:46,360 a whole lot about Titan surface 128 00:05:50,040 --> 00:05:48,070 thanks to that mission we actually do 129 00:05:52,740 --> 00:05:50,050 now know that there are hydrocarbon 130 00:05:54,300 --> 00:05:52,750 lakes and rivers and that the surface is 131 00:05:56,070 --> 00:05:54,310 actually pretty geologically young 132 00:05:57,870 --> 00:05:56,080 somewhere between a hundred and a 133 00:06:01,379 --> 00:05:57,880 billion 100 million and a billion years 134 00:06:04,890 --> 00:06:01,389 old but we can actually see these canals 135 00:06:07,170 --> 00:06:04,900 and rivers on the surface as well as a 136 00:06:11,070 --> 00:06:07,180 number of lakes at the northern pole of 137 00:06:13,290 --> 00:06:11,080 the moon as well and then also 138 00:06:16,020 --> 00:06:13,300 particularly interesting it has a rocky 139 00:06:17,760 --> 00:06:16,030 silicate core about 3,400 kilometers in 140 00:06:20,430 --> 00:06:17,770 diameter so it's a little bit bigger 141 00:06:23,790 --> 00:06:20,440 than Earth's moon but smaller than the 142 00:06:26,790 --> 00:06:23,800 earth but there's a lot of evidence that 143 00:06:30,089 --> 00:06:26,800 there is a subsurface ocean possibly a 144 00:06:32,070 --> 00:06:30,099 global ocean and what we think would 145 00:06:34,980 --> 00:06:32,080 allow for this is actually an ammonia 146 00:06:36,899 --> 00:06:34,990 water mixture so once you have enough 147 00:06:40,019 --> 00:06:36,909 ammonia in that water you can get this 148 00:06:45,060 --> 00:06:40,029 eutectic mixture that doesn't freeze out 149 00:06:46,379 --> 00:06:45,070 until much colder and so that also gives 150 00:06:48,680 --> 00:06:46,389 us the potential for a lot of 151 00:06:53,279 --> 00:06:48,690 interesting chemistry and importance for 152 00:06:54,390 --> 00:06:53,289 astrobiology the next rock that we're 153 00:06:57,209 --> 00:06:54,400 probably going to hear about is 154 00:06:59,579 --> 00:06:57,219 meteoroids and the IAU definition is 155 00:07:01,909 --> 00:06:59,589 incredibly specific it's a solid object 156 00:07:04,620 --> 00:07:01,919 moving in the interplanetary space of 157 00:07:06,570 --> 00:07:04,630 considerable size considerably smaller 158 00:07:11,579 --> 00:07:06,580 than an asteroid and considerably larger 159 00:07:13,920 --> 00:07:11,589 than an atom and so this actually gives 160 00:07:16,730 --> 00:07:13,930 us a pretty wide berth but most of these 161 00:07:20,370 --> 00:07:16,740 things are about 4.5 billion years old 162 00:07:22,079 --> 00:07:20,380 and perhaps most interestingly about 15 163 00:07:24,420 --> 00:07:22,089 thousand metric tons of these are 164 00:07:28,140 --> 00:07:24,430 delivered to earth every year and so 165 00:07:30,510 --> 00:07:28,150 these are a source of incoming material 166 00:07:33,689 --> 00:07:30,520 that can seed the planet with a lot of 167 00:07:37,079 --> 00:07:33,699 interesting material over you know the 168 00:07:38,879 --> 00:07:37,089 course of billions of years additionally 169 00:07:42,329 --> 00:07:38,889 most of them come from the asteroid belt 170 00:07:44,579 --> 00:07:42,339 about 99.8% of meteorites that we've 171 00:07:46,409 --> 00:07:44,589 found have come from there and so they 172 00:07:50,300 --> 00:07:46,419 can tell us a lot about the early solar 173 00:07:52,649 --> 00:07:50,310 system composition and some is well our 174 00:07:54,089 --> 00:07:52,659 cometary debris and so that's normally 175 00:07:57,480 --> 00:07:54,099 what we would refer to is like a meteor 176 00:07:59,640 --> 00:07:57,490 shower and then a very small number of 177 00:08:01,469 --> 00:07:59,650 them are ejected material from 178 00:08:04,469 --> 00:08:01,479 collisions with much larger body such as 179 00:08:06,829 --> 00:08:04,479 Mars in the moon and so these are some 180 00:08:11,189 --> 00:08:06,839 of the first hints that we got at what 181 00:08:15,749 --> 00:08:11,199 composition what the composition of Mars 182 00:08:17,159 --> 00:08:15,759 and the moon were after that we'll hear 183 00:08:19,589 --> 00:08:17,169 about some stromatolite some 184 00:08:20,879 --> 00:08:19,599 stromatolites are a little bit different 185 00:08:23,040 --> 00:08:20,889 than all the other rocks we'll be 186 00:08:24,930 --> 00:08:23,050 talking about one there here on earth 187 00:08:26,969 --> 00:08:24,940 which is exciting 188 00:08:30,240 --> 00:08:26,979 but they're built by living microbial 189 00:08:31,740 --> 00:08:30,250 colonies of cyanobacteria and on the 190 00:08:35,430 --> 00:08:31,750 modern earth they're actually found in 191 00:08:37,860 --> 00:08:35,440 only a very few select places such as 192 00:08:39,209 --> 00:08:37,870 Shark Bay and in the Caribbean and this 193 00:08:40,980 --> 00:08:39,219 is because they have to form in very 194 00:08:45,270 --> 00:08:40,990 hyper saline conditions and I'll talk a 195 00:08:46,829 --> 00:08:45,280 little more about that here but in the 196 00:08:47,429 --> 00:08:46,839 Precambrian area they were fairly 197 00:08:49,860 --> 00:08:47,439 ubiquitous 198 00:08:51,300 --> 00:08:49,870 all over the planet and they may date 199 00:08:54,059 --> 00:08:51,310 back all the way back to the Ark 200 00:08:55,590 --> 00:08:54,069 so there's some of the earliest forms of 201 00:08:57,480 --> 00:08:55,600 life that we see on the planet that we 202 00:09:01,230 --> 00:08:57,490 actually have like really nice records 203 00:09:03,749 --> 00:09:01,240 of and so the way these things form 204 00:09:07,019 --> 00:09:03,759 cyanobacteria are these photosynthetic 205 00:09:09,090 --> 00:09:07,029 species so they need to be able to get 206 00:09:14,069 --> 00:09:09,100 sunlight to grow but you get these mats 207 00:09:16,290 --> 00:09:14,079 of cyanobacteria and then they form on 208 00:09:20,280 --> 00:09:16,300 the shallow waters the deepest been 209 00:09:21,840 --> 00:09:20,290 found about 14 meters or 45 feet but as 210 00:09:24,269 --> 00:09:21,850 they do that they build up this mucus 211 00:09:27,239 --> 00:09:24,279 layer that can trap sediment or they can 212 00:09:29,939 --> 00:09:27,249 precipitate calcite as well but as that 213 00:09:32,040 --> 00:09:29,949 happens then they grow up through that 214 00:09:33,900 --> 00:09:32,050 layer and they start a new mat and then 215 00:09:35,489 --> 00:09:33,910 they grow out and then they collect more 216 00:09:36,960 --> 00:09:35,499 sediment and then they get another layer 217 00:09:38,160 --> 00:09:36,970 and they grow up through it and then 218 00:09:41,100 --> 00:09:38,170 they start another layer and they do 219 00:09:43,619 --> 00:09:41,110 this over and over again and so they 220 00:09:45,269 --> 00:09:43,629 trap a lot of the interesting material 221 00:09:47,340 --> 00:09:45,279 so they tell us a lot about what the 222 00:09:50,160 --> 00:09:47,350 conditions were when they were growing 223 00:09:54,210 --> 00:09:50,170 what was available what was settling out 224 00:09:55,650 --> 00:09:54,220 in the oceans but it's important that 225 00:09:58,470 --> 00:09:55,660 they need to be free of any sort of 226 00:10:00,869 --> 00:09:58,480 grazing species so if anything eats them 227 00:10:02,999 --> 00:10:00,879 then they can't build these rocks that's 228 00:10:05,040 --> 00:10:03,009 very problematic in today's oceans 229 00:10:07,139 --> 00:10:05,050 however pre-cambrian there weren't any 230 00:10:09,389 --> 00:10:07,149 fish or anything eating them so we have 231 00:10:10,590 --> 00:10:09,399 a lot of them around and you get them in 232 00:10:12,960 --> 00:10:10,600 all sorts of really interesting 233 00:10:18,449 --> 00:10:12,970 structures from domes to columns to 234 00:10:20,340 --> 00:10:18,459 splitting columns and then the last Rock 235 00:10:22,410 --> 00:10:20,350 we'll call it a rock iron-sulfur 236 00:10:25,769 --> 00:10:22,420 clusters think of them as very tiny 237 00:10:27,720 --> 00:10:25,779 rocks that are important in biology but 238 00:10:30,569 --> 00:10:27,730 they're made out of unsurprisingly iron 239 00:10:32,220 --> 00:10:30,579 and sulfur and they come in a really 240 00:10:34,019 --> 00:10:32,230 wide variety of different structures 241 00:10:36,150 --> 00:10:34,029 depending on how much iron and sulfur 242 00:10:39,210 --> 00:10:36,160 you have in them anywhere from very 243 00:10:44,030 --> 00:10:39,220 simple one in two atoms of iron and 244 00:10:46,470 --> 00:10:44,040 sulfur up to a much larger structures 245 00:10:48,449 --> 00:10:46,480 but interestingly they're found in a 246 00:10:49,889 --> 00:10:48,459 number of proteins in biology and 247 00:10:51,929 --> 00:10:49,899 there's at least three biosynthetic 248 00:10:54,210 --> 00:10:51,939 systems that have been identified for 249 00:10:58,199 --> 00:10:54,220 making these things in our biological 250 00:11:00,030 --> 00:10:58,209 systems and what's really interesting is 251 00:11:03,030 --> 00:11:00,040 they play a really important role in 252 00:11:04,710 --> 00:11:03,040 redox oxidation reactions in 253 00:11:06,869 --> 00:11:04,720 mitochondria 254 00:11:08,819 --> 00:11:06,879 both complex 1 & 2 an oxidative 255 00:11:11,939 --> 00:11:08,829 phosphorylation have multiple iron 256 00:11:14,160 --> 00:11:11,949 sulfur clusters in them they can also 257 00:11:17,220 --> 00:11:14,170 act as catalytic centers for a lot of 258 00:11:19,400 --> 00:11:17,230 biological activity and because of this 259 00:11:22,499 --> 00:11:19,410 they've been suggested as playing an 260 00:11:27,059 --> 00:11:22,509 important role in the origin of life on 261 00:11:30,720 --> 00:11:27,069 Earth and so with that I will thank you 262 00:11:32,790 --> 00:11:30,730 guys for your time and hand things over 263 00:11:34,230 --> 00:11:32,800 to the experts that are going to be 264 00:11:38,690 --> 00:11:34,240 giving talks dare I call them the rock